In a world increasingly aware of the environmental impact of single – use plastics, biodegradable bags have emerged as a promising solution. These bags offer a glimmer of hope in the fight against plastic pollution, but have you ever stopped to wonder how do biodegradable bags work? Let’s dive into the fascinating science behind biodegradable bags.
What are Biodegradable Bags?

Biodegradable plastics are often seen as a ray of hope for solving the problem of plastic pollution. The biggest difference between biodegradable plastics and traditional plastics we use in daily life is that biodegradable plastics can decompose in a relatively short time.
It should be clear that “biodegradable” is not the same as “instant decomposition”. The decomposition process still takes a certain amount of time, and the length of this time depends largely on how the plastic is discarded and the environment in which it is located.
The Problem with Traditional Plastic Bags

Before we explore the workings of biodegradable bags, it’s essential to understand the problem with traditional plastic bags. Made primarily from polyethylene, a synthetic polymer derived from fossil fuels, these bags are incredibly durable. While durability is a virtue in some cases, it becomes a major drawback when it comes to disposal.
Traditional plastic bags can persist in the environment for hundreds of years, clogging landfills, littering our streets, and polluting our oceans. They break down into microplastics over time, which then find their way into the food chain, posing a serious threat to wildlife and human health.
Biodegradability is the ability of a material to be broken down by natural processes into simpler substances. For biodegradable bags, this means that they can be decomposed by microorganisms such as bacteria, fungi, and algae. The end products of this decomposition are typically carbon dioxide, water, and biomass, which are harmless to the environment. This is in stark contrast to traditional plastic bags, which do not break down easily and leave behind harmful residues.
How Do Biodegradable Bags Work?

Microbial Action
The primary mechanism by which biodegradable bags break down is through the action of microorganisms. These tiny organisms are present in soil, water, and the air, and they play a crucial role in the natural recycling of organic matter.
When a biodegradable bag is exposed to the environment, microorganisms attach themselves to the surface of the bag and start to secrete enzymes. These enzymes are like molecular scissors that cut the long polymer chains in the bag’s material into smaller pieces.
For example, if the bag is made of a starch-based material, amylase enzymes secreted by bacteria break down the starch into simple sugars. These sugars are then absorbed by the bacteria as a source of energy, and in the process, the bag starts to disintegrate. Similarly, if the bag is made of poly(lactic acid) (PLA), specific microorganisms produce enzymes that can break the PLA polymer into lactic acid monomers, which can then be further metabolized.
Environmental Factors
The rate of decomposition of biodegradable bags is also influenced by various environmental factors.
Temperature: Warmer temperatures generally accelerate the decomposition process. Microorganisms are more active at higher temperatures, and the chemical reactions involved in degradation occur more rapidly. For instance, in tropical regions with warm climates, biodegradable bags may break down much faster compared to colder regions.
Moisture: Adequate moisture is essential for the growth and activity of microorganisms. In dry environments, the decomposition of biodegradable bags can be significantly slowed down. Moisture also helps in the hydrolysis of polymers, which is an important step in the degradation process. For example, water molecules can react with the chemical bonds in the bag’s material, breaking them apart and making it easier for microorganisms to attack.
Oxygen: Most biodegradable bags require oxygen for complete decomposition. Aerobic microorganisms, which need oxygen to survive, are responsible for the breakdown of the bag’s material. In anaerobic conditions, such as in the deep layers of a landfill where oxygen is scarce, the decomposition process may be incomplete or much slower. However, some biodegradable materials are designed to be anaerobically biodegradable, meaning they can be broken down by anaerobic microorganisms.
Types of Biodegradable Bags

Starch-Based Bags
Starch-based biodegradable bags are made from starches sourced from plants like corn, potatoes, or wheat. These bags are relatively easy to produce and are often used for applications such as food packaging. When exposed to the environment, the starch in the bag is quickly attacked by microorganisms. As mentioned earlier, amylase enzymes break down the starch into sugars, and the bag starts to degrade. However, starch-based bags may have some limitations. They can be sensitive to moisture, and if not stored properly, they may become brittle or lose their structural integrity.
PLA-Based Bags
Poly(lactic acid) (PLA) is a popular material for biodegradable bags. Derived from renewable resources such as corn starch or sugarcane, PLA has good mechanical properties, making it suitable for a wide range of applications, from shopping bags to food containers.
In the presence of heat, moisture, and microorganisms, PLA starts to hydrolyze, breaking down into lactic acid. The lactic acid can then be further metabolized by microorganisms into carbon dioxide and water. PLA-based bags are often used in applications where a more durable and aesthetically pleasing biodegradable option is required.
PHA-Based Bags
Polyhydroxyalkanoates (PHA) are natural polymers produced by microorganisms during fermentation. PHA-based biodegradable bags are highly biodegradable and can decompose in a variety of environments, including soil, water, and marine settings. They are also biocompatible, which means they are less likely to cause harm to living organisms in the ecosystem. The decomposition of PHA bags is mainly driven by the action of microorganisms that can break down the PHA polymer into smaller molecules. PHA-based bags are often used in applications where environmental compatibility is a top priority, such as medical waste disposal or packaging for sensitive products.
The Role of Additives in Biodegradable Bags
Some biodegradable bags contain additives that can enhance their performance or decomposition rate.
Antioxidants: These are added to prevent the premature degradation of the bag’s material during storage and transportation. Antioxidants work by scavenging free radicals that can cause the polymer chains to break down prematurely. This ensures that the bag remains in good condition until it is ready to be used.
UV Stabilizers: Since exposure to sunlight can accelerate the degradation of some biodegradable materials, UV stabilizers are added to protect the bags from the harmful effects of ultraviolet (UV) radiation. UV stabilizers absorb or reflect UV rays, preventing them from reaching the polymer and causing damage.
Pro-Degradants: Some biodegradable bags may contain pro-degradants, which are substances that can accelerate the decomposition process. Pro-degradants work by promoting the breakdown of the polymer chains, either by initiating chemical reactions or by making the material more susceptible to microbial attack. However, the use of pro-degradants is a subject of debate, as some concerns have been raised about the potential environmental impact of the breakdown products.
Real-World Examples and Success Stories
There are many real-world examples of the successful use of biodegradable bags. In some cities, supermarkets have replaced traditional plastic bags with biodegradable ones, reducing the amount of plastic waste going into landfills.
For instance, in a few European cities, the adoption of biodegradable shopping bags has led to a significant decrease in the amount of plastic litter in the streets and waterways. Some food companies have also started using biodegradable packaging for their products, which not only reduces their environmental footprint but also appeals to environmentally conscious consumers.
Challenges and Limitations
Despite their many advantages, biodegradable bags also face some challenges. One of the main challenges is the lack of proper infrastructure for their disposal. In many areas, there are no dedicated composting facilities, and biodegradable bags may end up in landfills or incinerators, where they may not decompose properly.
Another challenge is the cost. Biodegradable bags are often more expensive to produce than traditional plastic bags, which can be a barrier to their widespread adoption. There are also concerns about the potential environmental impact of some biodegradable materials, especially if they are not fully understood or if they are not disposed of properly.
Do Biodegradable Plastic Bags Help The Planet?

The future of biodegradable bags looks promising. As technology continues to advance, we can expect to see the development of more efficient and cost-effective biodegradable materials. Research is also being done to improve the infrastructure for the disposal of biodegradable bags, making it easier for consumers to recycle or compost them. In addition, as consumers become more environmentally conscious, the demand for biodegradable bags is likely to increase, driving further innovation and growth in the industry.
Conclusion
In conclusion, biodegradable bags offer a practical and sustainable solution to the problem of plastic pollution. By understanding how they work, we can make more informed choices as consumers and support the development and use of these eco-friendly alternatives. Whether it’s choosing a biodegradable shopping bag at the grocery store or advocating for the use of biodegradable packaging in our communities, every small step counts in the fight to protect our planet.